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This material is based upon work supported by the National Science Foundation under Grant Nos. 9726498 and 0108734 and by the Robert A. Welch Foundation. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation or the Robert A. Welch Foundation.
Heavy Particle CollisionsThe processes studied include elastic scattering of keV energy ions and neutrals, charge transfer of keV energy ions, and electron capture and loss reactions of keV neutrals. The focus of much previous work has been charge transfer of protons and oxygen ions with atomic oxygen. These processes are aeronomically very important and are also particularly difficult to deal with experimentally. Other work has involved measuring the differential charge transfer cross sections for state-selected oxygen ions. These studies are also directly applicable to the precipitation of energetic oxygen ions into the earth's upper atmosphere. Currently, experiments are underway to measure cross sections for electron capture and loss by O atoms in H2, N2, O2, and He. Electron-Impact IonizationAlthough the importance of electron-impact ionization has long been recognized, and the process has been studied experimentally since the 1920s, the total cross sections for many processes are only known to within a factor of two, and the cross sections for dissociative processes are known even less accurately. We have built an apparatus designed specifically to make accurate electron-impact ionization measurements. Over the past several years this apparatus has been utilized to study the following targets: He, Ne, Ar, Kr, Xe, H2, N2, O2, CO2, SO2, CH4, H2O, NO2, CO, CF4, SF6, NH3, and the methyl halides (CH3X, X=F, Cl, Br, I). Recent work has involved the simple alcohols (CH3OH, C2H5OH, C3H7OH), N2O, H2S, and CS2. Currently, CCl4 and CCl2F2 are being studied. InstrumentationAs is often the case in experimental physics, 'in house' development of technology is critical to the success of a project. Our group carried out some of the earliest work on the characterization and use of the position-sensitive detectors (PSDs) which are now an integral part of each of the apparatuses in our laboratory. More recently we have perfected a technique to use a commercial capacitance manometer at pressures much lower than previously thought possible. We have also worked on the developmentment of an accurate atomic oxygen sensor.
Charge transfer cross sections Electron Capture and Loss cross sections Direct scattering cross sections Electron-impact ionization cross sections
Physics and Astronomy | Rice Quantum Institute| Rice Space Institute
Updated July 1, 2004 |