PUBLICATIONS
1967-1989
ROBERT H. HAUGE

1967

1)"Thermodynamics of Vaporization of GeF2, SnF2, and PbF2 and Bond Dissociation Energies of Group IVA
Fluorides
," RH Hauge, J. Hastie, K. Zmbov and J.L. Margrave. Third Intl. Symp. on High Temperature
Technology, Asilomar, Canada, September 1967

2)"Infrared Spectrum, Force Constants and Thermodynamic Functions of SiF2," R.H. Hauge, V.M. Khanna,
R.F. Curl, Jr., and J.L. Margrave. J. Chem. Phys. 27, 5031 (1967)

1968

3)"Formation of Polymeric (GeF2) in the Vapor Phase Over GeF2," R.H. Hauge, J. Hastie, K. Zmbov and
J.L. Margrave. Inorg. Chem., 7, 608 (1968)

4)"The Ultraviolet Absorption Spectra of GeF2," R.H. Hauge, V. Khanna and J.L. Margrave. J. Mol. Spec.,
27, 143 (1968)

5) "Infrared Vibrational Properties of GeF2," R.H. Hauge, J.W. Hastie and J.L. Margrave. J. Phys. Chem., 72,
4492 (1968)

6) "Ultraviolet Absorption Spectra of Gaseous SnF2 and PbF2," R.H. Hauge, J.W. Hastie and J.L. Margrave.
J. Phys. Chem., 72, 3510 (1968)

1969

7)"Infrared Spectra and Geometry of SO2 and SeO2 in Rare Gas Matrices," R.H. Hauge, J.W. Hastie and
J.L. Margrave. J. Inorg. Nucl. Chem., 31, 281 (1969)

8)"Ultraviolet Spectra and Electronic Structure of Group IVA Dichlorides," R.H. Hauge, J.W. Hastie and
J.L. Margrave. J. Mol. Spect., 29, 152 (1969)

9)"Infrared Spectra of SiF2 in Neon and Argon Matrices," R.H. Hauge, J.W. Hastie and J.L. Margrave.
J. Am. Chem
. Soc. 91, 2536 (1969)

10)"Infrared Spectra and Geometry of the Difluorides of Co, Ni, Cu and Zn Isolated in Neon and Argon
Matrices
," R.H. Hauge, J.W. Hastie and J.L. Margrave. High Temp. Sci. 1, 76 (1969)

11)"Infrared Spectra and Geometry of TiF2 and TiF2 in Rare Gas Matrices," R.H. Hauge, J.W. Hastie and
J.L. Margrave. J. Chem. Phys. 51, 2648 (1969)

12)"Reactions and Structures of Isolated SiO Species at Low Temperatures from Infrared Spectra," R.H.
Hauge, J.W. Hastie and J.L. Margrave. Inorganica Chemica Acta 3, 601 (1969)

13)"Vaporization, Thermodynamics and Structures of Species in the Tellurium-Oxygen System," D.W.
Muenow, R.H. Hauge, J.W. Hastie, R.G. Bautista and J.L. Margrave. Trans. Faraday Soc. 65, 3210 (1969)

14)"Vibrational Frequencies and Valence Force Constants of First-row Transition-metal Di-fluorides," R.H.
Hauge, J.W. Hastie and J.L. Margrave. Chem. Comm., 1452 (1969)

1970

15)"Matrix Isolation Spectroscopy," R.H. Hauge, J.W. Hastie and J.L. Margrave. Spectroscopy in Inorganic
Chemistry
, Vol. 1, Ed. J.R. Ferraro and C.N.R. Rao, Academic Press, pp. 57-106, 1970

16)"High Temperature Chemistry: Stabilities and Structures of High Temperature Species," R.H. Hauge,
J.W. Hastie and J.L. Margrave. Ann. Rev. Phys. Chem. 21, 475 (1970)

1971

17)"Force Constants and Geometries of Matrix Isolated Rare Earth Trifluorides," R.H. Hauge, J.W. Hastie
and J.L. Margrave. J. Less-Common Metals 23, 359 (1971)

18)"Infrared Spectra and Geometries of Heavy Metal Halides: SrCl2, BaCl2, EuCl2, EuF2, and UCl2, EuF2,"
R.H. Hauge, J.W. Hastie and J.L. Margrave. High Temp. Sci. 3, 56 (1971)

19)"Infrared Spectra and Geometries for the Dichlorides of Ca, Sc, Ti, V, Cr, Mn, Fe and Ni," R.H. Hauge,
J.W. Hastie and J.L. Margrave. High Temp. Sci. 3, 257 (1971)

20)"Matrix-Isolation Study of the Pyrolysis of Bromosubstituted Organomercury Compounds. Infrared
Spectra of the Chlorobromocarbene and Free Radicals CCl2MBr and CClBr2
," A.K. Maltsev, P.M.
Nefedov, D. Seyferth, R.H. Hauge, and J.L. Margrave. J. Phys. Chem. 75, 3984 (1971)

21)"Pyrolysis of Organomercury Compounds: Investigation by the Method of Matrix Isolation," A.K.
Maltsev, R.G. Mikaelian, O.M. Nefedov, R.H. Hauge, and J.L. Margrave. Proceedings, Nat'l. Acad. Sci. USA,
68, 12, pp. 3238-3241, December 1971

1972

22)"Stabilities of Gaseous Diatomic Sulfides," R.H. Hauge, J.L. Margrave. High Temp. Sci. 4, 170 (1972)
23)"Vacuum U-V Spectra of SiF2 and GeF2," J.L. Gole, R.H. Hauge, J.W. Hastie and J.L. Margrave.
J. Mol. Spec. 43, 441 (1972)

24)"The IR Spectrum of Matrix Isolated SiBr2 and SiCl2," R.H. Hauge, G. Maass and J.L. Margrave. Z. fur
Anorg. Und Allg. Chemie
392 295 (1972)

25)"IR Study of Matrix Isolated Lithium Isocyanide," Z.K. Ismail, R.H. Hauge and J.L. Margrave.
J. Chem. Phys
. 57, 5137 (1972)

1973

26)"The IR Spectra of Matrix-Isolated NaCN and KCN," Z.K. Ismail, R.H. Hauge and J.L. Margrave.
J. Mol. Spec
. 45, 304 (1973)

27)"Infrared Spectra of the Alkali Metal Cyanides in the Solid State," Z.K. Ismail, R.H. Hauge and
J.L. Margrave. Appl. Spec. 27, 93 (1973)

28)"Infrared Spectra of Matrix Isolated ZrF2, ZrF3 and ZrF4 Species," R.H. Hauge, J.W. Hastie and J.L.
Margrave. High Temp. Sci. 5, 89 (1973)

29)"Infrared Spectra of Matrix Isolated Tin and Lead Difluorides," R.H. Hauge, J.W. Hastie and
J.L. Margrave. J. Mol. Spec. 45, 420 (1973)

30)"Infrared Spectra of Sodium and Potassium Fluorides by Matrix Isolation," Z.K. Ismail, R.H. Hauge
and J.L. Margrave. J. Inorg. Nucl. Chem. 35, 3201 (1973)

31)"Infrared Spectra of Matrix-Isolated Species in the Gallium-Fluorine System," R.H. Hauge, J.W. Hastie
and J.L. Margrave. J. Fluorine Chem. 3, 285 (1973)

1974 (no publications)

1975

32)"IR Spectra of Matrix Isolated MgF2," A.S. Kana'an, R.H. Hauge and J.L. Margrave. J.C.S. Trans.
Farad. II
, 71, 1082 (1975)

33)"Geometries and Entropies of Metal Trifluorides from Infrared Spectra: ScF2, YF3, LaF3, EuF3,
and GdF3
," R.H. Hauge, J.W. Hastie and J.L. Margrave. J. Less-Common Metals 39, 309 (1975)

34)"IR Studies of Matrix Isolated Sodium and Potassium Chloride and Cyanide Dimers," Z.K. Ismail,
R.H. Hauge and J.L. Margrave. J. Mol. Spectr. 54, 402 (1975)

1976

35)"IR Matrix Study of Reactions of UF4 with Fluorine," K.R. Kunze, D. Hamill , R.H. Hauge and
J.L. Margrave. J. Chem. Phys. 65, 2026 (1976)

36)"Infrared Spectra of Matrix-Isolated Species: Reactions of MgF2 with Group I-Group II Fluorides," A.
Kana'an, R.H. Hauge and J.L. Margrave. J. Chem. Soc., Faraday II, 72, 1991 (1976)

1977

37)"Matrix Isolation IR and EPR Studies of Reaction Intermediates: Lithium Metal Reactions with H2O,
CH3OH, and NR3
," P.F. Meier, R.H. Hauge and J. L. Margrave. Proc., Berlin Symposium on Matrix Isolation
Spectroscopy, West Berlin, Germany, June 21-24, 1977, Berichte der Bunsengesellschaft, Physikalische
Chemie 82, 102 (1978).

38)"Reactions of Small Hydrocarbons in Fluorine Matrices," S.E. Gransden, J. Wang, R.H. Hauge and J.L.
Margrave. Proc., Berlin Symposium on Matrix Isolation Spectroscopy, West Berlin, Germany, June 21-24,
1977, Berichte der Bunsengesellschaft, Physikalische Chemie, 82, 104 (1978)

39)"Studies of Matrix-Isolated Uranium Tetrafluoride and its Interactions with Frozen Gases," K.R. Kunze,
D. Hamill, R.H. Hauge and J.L. Margrave. J. Phys. Chem. 81, 1664 (1977)

40)"Interactions of Carbon Monoxide with Alkali, Alkaline Earth, Transition Metal and Lanthanide
Fluorides in an Argon Matrix
," S.E. Gransden, R.H. Hauge and J.L. Margrave. Proc., Symp. on Metal Halide
Chemistry, Electrochemical Society, Atlanta, Georgia, Vol. 78-1, pp. 310-19, Oct. 14, 1977

41)"Low Temperature Matrix IR and EPR Spectroscopic Studies of Reaction Intermediates in Reactions of
Alkali Metal Atoms with Water, Carbon Monoxide, Acetylene, Ethylene and Carbon Dioxide
," R.H. Hauge,
and J.L. Margrave. Argonne Nat'l Labs. Report, ANL-77-21, pp 283-8, (1977)

1978

42)"Co-condensation Reactions of Uranium Tetrafluoride and Hexafluoride with Alkali Metals and Alkali-
metal Fluorides in Low Temperature Argon Matrices
," K.R. Kunze, D. Hamill, R.H. Hauge and J.L. Margrave.
J. Chem. Soc
., Dalton Trans., 433-440 (1978)

43)"Electron Spin Resonance Studies of the Reaction of Lithium Atoms and Lewis Bases in Argon Matrices:
Formation of Reactive Intermediates with Water and Ammonia
," P.F. Meier, R.H. Hauge and J.L. Margrave.
J. Am. Chem. Soc
. 100, 2108 (1978)

44)"Matrix Isolation Infrared and Electron Paramagnetic Resonance Spectroscopic Studies of the Reaction
of Lithium with Silicon Tetrafluoride
," D.L. Perry, P.F. Meier, R.H. Hauge and J.L. Margrave. Inorg. Chem. 17,
1364 (1978)

45)"Matrix Isolation Studies of Magnesium and Iron Atom Reactions with Water," S.E. Gransden, J.W.
Kauffman, R.H. Hauge and J.L. Margrave. Proc., 10th Materials Research Symp. on Characterization of High
Temperature Vapors and Gases, Sept. 18-22, 1978

46)"Matrix Isolation Studies of High Temperature Species," R.H. Hauge and J.L. Margrave. Proc., 10th
Materials Research Symp. on Characterizations of High Temperature Vapors and Gases, Sept. 18-22, 1978

1979

47)"The Interaction of Carbon Monoxide with Alkali, Alkaline Earth, Transition Metal and Lanthanide
Fluorides in an Argon Matrix
," S.E. Gransden, R.H. Hauge and J.L. Margrave. J. Chem. Soc., Dalton 5, 745-
748 (1979)

48)"Reactions of Main Group IV Species with Organic Reagents. I. Tin and Tin (II) Fluoride Reactions with
Ethylene
," P.F. Meier, D.L. Perry, R.H. Hauge and J.L. Margrave. Inorg. Chem. 18, 2051-2053 (1979)

49)"Studies of the Reactions of Molecular Fluorine with Methane, Acetylene, Ethylene, Allene, and Other
Small Hydrocarbons in Matrices at Low Temperatures
," S. Gransden, J. L-F Wang, R.H. Hauge and J.L.
Margrave. J. Am. Chem. Soc. 101, 6950-6954 (1979)

50)"Low Temperature Chlorination and Bromination of UF4 in Argon Matrices," K.R. Kunze, R.H. Hauge
and J.L. Margrave. Inorg. Nucl. Chem. Letters 15, 65-68 (1979)

51)"High Temperature Science: Future Needs and Anticipated Developments," R.H. Hauge, G.Rosenblatt
and J.L. Margrave (co-author-editorial advisor). Committee on High Temp. Sci. and Tech., Nat'l Research
Council, Nat'l Academy of Sciences, Washington, D.C. (1979)

1980

52)"High Temperature Techniques," R.H. Hauge and J.L. Margrave. Chemical Experimentation Under
Extreme Conditions
, Ed. A. Weissberger and B. Rossiter, John Wiley & Sons, Inc. Chap. IX, pp 277-360,
(1980)

53)"Synthesis of Fluorine Resistant Materials for Use at High Temperatures," R. Ashcraft, D. McDonald,
R.B. Badachhape, R.H. Hauge and J.L. Margrave. Union Carbide Final Report, Subcontract 7623, DOE W-
7405-eng-26 (1980)

54)"Direct Fluorination of Organic Compounds," R.B. Badachhape, R.J. Lagow, R.H. Hauge and J.L.
Margrave. Encyclopedia of Chemical Technology, Third Ed., Ed. M. Grayson, John Wiley & Sonc, Inc.,
10, pp. 840-856 (1980)

55)"Infrared Matrix-Isolation Studies of the Interactions and Reactions of Group IIIA Metal Atoms with
Water
," J.W. Kauffman, R.H. Hauge and J.L. Margrave. J. Am. Chem. Soc. 102, 19, 6005-6011 (1980)

56)"Carbon-Carbon Bond Formation in the Reaction of Calcium Atoms with Ethers," W.E. Billups, M.M.
Konarski, R.H. Hauge and J.L. Margrave. J. Am. Chem. Soc., 102, 3649 (1980)

57)"Activation of Dimethyl Ether with Transition Metal Atoms," W.E. Billups, M.M. Konarski, R.H. Hauge
and J.L. Margrave. Tetrahedron Letters, 21, 3861-3864 (1980)

58)"Activation of Methane with Photo-excited Metal Atoms," W.E. Billups, M.M. Konarski, R.H. Hauge and
J.L. Margrave. J. Am. Chem. Soc. 102, 7393 (1980)

59)"Activation of Dimethyl Ether with Barium and Strontium Atoms," W.E. Billups, M.M. Konarski, R.H.
Hauge and J.L. Margrave. J. Organometal. Chem. 194, C22-C24 (1980)

60)"Interactions of Pure Metals with Water," J.W. Kauffman, R.H. Hauge and J.L. Margrave. Proc., Materials
Research Council, Summer Conf., La Jolla, CA, 231-39 (1980)

61)"Gaseous Molecules with Very High Molecular Weights," J.P. Bell, J.G. Edwards, R. McFarland, R.H.
Hauge and J.L. Margrave. Proc., Materials Research Council, Summer Conf., La Jolla, CA, 240-245, July 1980

62)"Metal Hydride Analysis, Hydroxides and Alkoxy Derivatives as Propellant Additives," J.W. Kauffman,
M.M. Konarski, R.H. Hauge and J.L. Margrave. Proc., Materials Research Council, Summer Conf., La Jolla, CA,
376-380, July 1980

63)"Matrix Isolation Studies of the Reactions of Metal Atoms with Water," S. Gransden, J.W. Kauffman, R.H.
Hauge and J.L. Margrave. High Temperature Science 13, 338 (1980)

1981

64)"Matrix Isolation Infrared Studies of Metal Atom-Water Reactions," J.W. Kauffman, L. Fredin, R.H.
Hauge and J.L. Margrave. Proc., Symp. on High Temperature Chemistry, ACS Advances in Chemistry Series,
Ed. J.L. Gold, pp. 363-376 (1981)

65)"Electronic Absorption Spectroscopy of Aluminum Metal Atom Hydration Products Isolated in Rare Gas
Matrices at 15K
," M.A. Douglas, R.H. Hauge and J.L. Margrave. Proc., Symp. on High Temperature
Chemistry, ACS Advances in Chemistry Series, Ed. J.L. Gole, pp. 347-354 (1981)

66)"Infrared Matrix Isolation Studies of Group IVA Metals with Water," J.W. Kauffman, R.H. Hauge and
J.L. Margrave. Proc., Symp. on High Temperature Science, ACS Advances in Chemistry Series, Ed. J.L. Gole,
pp. 355-362 (1981)

67)"Matrix Isolation Studies on the Lithium-Induced Reductive Coupling of Carbon Dioxide," J.W. Kauffman,
N.A. Rao, M.M. Konarski, J.P. Bell, W.E. Billups, R.H. Haugeand J.L. Margrave. J. Chem. Soc., Chem. Comm.,
24, 1258-1260 (1981)

68)"New Reactions of Astrochemical Interest," J.W. Kauffman, M.M. Konarski, W.E. Billups, R.H. Hauge
and J.L. Margrave. Proc., DARPA Materials Research Council Summer Conference, pp. 242-249, July 1981

69)"Infrared Study of Matrix-Isolated Lithium Isocyanide Dimers," Z.K. Ismail, R.H. Hauge and J.L.
Margrave. High Temperature Science 14, 197-206 (1981)

1982

70)"Synthetic Inorganic Chemistry with Metal Atoms in Low Temperature Matrices," L. Fredin, Z.H. Kafafi,
W.E. Billups, R.H. Hauge and J.L. Margrave. Proc., Symp. on Inorganic Chemistry in the Year 2000, pp. 329-331
(1982)

71)"Matrix Isolation Studies of the Reactions of Silicon Atoms: I. Interaction with Water: The Infrared
Spectrum of Hydroxysilylene HSiOH
," Z.K. Ismail, L. Fredin, J.W. Kauffman, R.H. Hauge and J.L. Margrave.
J. Chem. Phys. 77(4), 1617-1625 (1982)

72)"Matrix Isolation Studies of the Reactions of Silicon Atoms. II. Infrared Spectrum and Structure of
Matrix-Isolated Fluorosilylene: HSiF
," Z.K. Ismail, L. Fredin, R.H. Hauge and J.L. Margrave. J. Chem. Phys.
77(4), 1626-1631 (1982)

1983

73)"Studies of the Reactions of Lithium Atoms with Methyl Cyanide and Methyl Isocyanide in Inert Gas
Matrices
," Z.H. Kafafi, R.H. Hauge and J.L. Margrave. Polyhedron 2, No. 3, 167-169 (1983)

74)"Infrared Matrix Isolation Spectrum of the Si2C Molecule," Z.H. Kafafi, L. Fredin, R.H. Hauge and J.L.
Margrave. J. Phys. Chem. 87, 797-800 (1983)

75)"Neutral Gaseous Molecules with Molecular Weights Higher Than 4000," J.P. Bell, J.G. Edwards, R.H.
Hauge and J.L. Margrave. J. Phys. Chem. 87, 1157-1160 (1983)

76)"Electronic Absorption and Emission Studies of the Group IIIA Metal Suboxides Isolated in Cryogenic
Rare Gas Matrices
," M.A. Douglas, R.H. Hauge and J.L. Margrave. High Temperature Science 16,
35-54 (1983)

77)"Matrix Isolation Studies by Electronic Spectroscopy of Group IIIA Metal Water Photochemistry," M.A.
Douglas, R.H. Hauge and J.L. Margrave. J. Chem. Soc., Faraday Trans., 79, 1, 1533-53 (1983)

78)"Electronic Absorption Studies of the Group IIIA Metal Dimers Isolated in Cryogenic Matrices," M.A.
Douglas, R.H. Hauge and J.L. Margrave. J. Phys. Chem. 87, 2945-2947 (1983)

79)"Carbon Dioxide Activation by Lithium Metal. I. Infrared Spectra of Li+CO2- Li+C2O4- and
Li2++CO2= in Inert Gas Matrices
," Z.H. Kafafi, W.E. Billups, R.H. Hauge and J.L. Margrave. J. Am.
Chem. Soc
., 105, 3886-3893 (1983)

80)"Activation of Ethane, Propane and Cyclopropane by Photoexcited Iron Atoms," Z.H. Kafafi, L. Fredin,
W.E. Billups, R.H. Hauge and J.L. Margrave. Chem. Comm., 1230-1231 (1983)

81)"Reflectivities and Emissivities of Refractory Materials at Various Wavelengths and Temperatures," L.
Fredin, R.H. Hauge and J.L. Margrave. Proc., Fourth Japan Symp. on Thermophysical Properties, Tokyo,
p. 107, Oct. 24-26, 1983

82)"Studies of Initial Reaction Steps in the Gasification of Coal and Selected Model Compounds," C.J. Chu,
L. Fredin, R.B. Badachhape, R.H. Hauge and J.L. Margrave. Final Technical Progress Report, Dept. of Energy,
DE-FG22-81PC40792 (1983)

1984

83)"Carbon Dioxide Activation by Alkali Metals. II. Infrared Spectra of M+CO2- and M2++CO2= in Argon
and Nitrogen Matrices
," Z.H. Kafafi, W.E. Billups, R.H. Hauge and J.L. Margrave. Inorg. Chem., 23, 177-183
(1984)

84)"The Identification and Chemistry of Species Resulting From the Rapid Pyrolysis of Small Coal Particles
in Vacuum and in the Presence of Reactive Gases
," C.J. Chu, L. Fredin, R.H. Hauge and J.L. Margrave. Am.
Chem. Soc
., Div. Fuel Chem., 28, 35-43 (1984)

85)"Reactions of Iron Atoms and Iron Dimers with Methane, Ammonia and Hydrogen Fluoride in Low
Temperature Matrices
," J.W. Kauffman, R.H. Hauge and J.L. Margrave. High Temperature Science (Brewer
Issue) 17, 237 (1984)

86)"Infrared Matrix Isolation Studies of the Interactions of Mg, Ca, Sr and Ba Atoms and Small Clusters
with Water
," J.W. Kauffman, R.H. Hauge and J.L. Margrave. High Temperature Science, 18, 97-118 (1984)

87)"Activation of Hexafluoroethane by Calcium Atoms," W.E. Billups, J.P. Bell, R.H. Hauge and J.L. Margrave.
J. Fluorine Chem
., 26, (1984) 165-167

88)"Direct Fluorination," R.B. Badachhape, R.J. Lagow, R.H. Hauge and J.L. Margrave. Kirk-Othmer Concise
Encyclopedia of Chemical Technology
, John Wiley (N.Y.), p. 506 (1984)

89)"Fundamental Studies of Materials Response to Laser Radiation," M.J. Berry, R.H. Hauge and J.L.
Margrave. Final Rice University Technical Report, DARPA-BDM, Laser Countermeasures Program, Oct. (1984)

90)"Pyrolysis Studies of Fluorinated Illinois #6," C.J. Chu, R.B. Badachhape, R.H. Hauge and J.L. Margrave.
Fuel, 29, 49-57 (1984)

91)"Pyrolysis Studies of Illinois #6 and Its Tar Using Matrix Isolation FTIR Spectroscopy," C.J. Chu,
L. Fredin, R.H. Hauge and J.L. Margrave. ACS, Division of Fuel Chemistry, Preprints, 29:2 p. 49, (1984)

1985

92)"The Isolation and Characterization of Iron Methylene, FeCH2 via FTIR Matrix Isolation," S.C. Chang,
Z.H. Kafafi, W.E. Billups, R.H. Hauge and J.L. Margrave. J. Am. Chem. Soc. 107, 1447 (1985)

93)"Matrix Isolation Studies of the Reactions of Silicon Atoms With Molecular Hydrogen. The Infrared
Spectrum of Silylene
," L. Fredin, Z.H. Kafafi, R.H. Hauge and J.L. Margrave. J. Chem. Phys. 82, 3542-5 (1985)

94)"Studies of Pyrolysis Processes of Illinois #6 Coal and its Tar Using Matrix Isolation FTIR
Spectroscopy
," C.J. Chu, L. Fredin, R.H. Hauge and J.L. Margrave. Proc., HTERM Conf., High Temperature
Science
, 20, 51-73, (1985)

95)"Matrix Isolation Studies of the Iron/Cyclopentadiene System. Infrared Detection of
Cyclopentadieneyliron Hydride
," D.W. Ball, Z.H. Kafafi, R.H. Hauge and J.L. Margrave. Inorg. Chem., 24,
3708-3710, (1985)

96)"Reactions of Atomic Scandium, Titanium and Vanadium with Molecular Water at 15 K," J.W. Kauffman,
R.H. Hauge and J.L. Margrave. J. Phys. Chem., 89, 3547-3552, (1985)

97)"Studies of Reactions of Cr, Mn, Fe, Co, Ni, Cu and Zn with Molecular Water at 15 K," J.W. Kauffman,
R.H. Hauge and J.L. Margrave. J. Phys. Chem., 89, 3541-3547, (1985)

98)"Interactions of Atomic and Molecular Iron with Methane in an Argon Matrix at 15 K," Z.H. Kafafi,
R.H. Hauge and J.L. Margrave. J. Am. Chem. Soc., 107:21, 6134, (1985)

99)"Photochemistry of Iron Atoms and Dimers with Ethylene in Cryogenic Matrices. The FTIR Spectrum of
Ethenyliron Hydride
," Z.H. Kafafi, R.H. Hauge and J.L. Margrave. J. Am. Chem. Soc., 107, 7550-7559 (1985)

100)"Matrix Isolation Studies of the Reactions of Iron Atoms and Iron Dimers with Acetylene in an Argon
Matrix. The FTIR Spectrum of Ethynyliron Hydride
," E. Kline, Z.H. Kafafi, R.H. Hauge and J.L. Margrave.
J. Am. Chem. Soc
., 107, 7559-7562,(1985)

101)"Activation of O-H and C-O Bonds of Methanol by Photoexcited Iron Atoms," M. Park, Z.H. Kafafi, R.H.
Hauge and J.L. Margrave. Chem. Comm., 1570-1571, (1985)

102)"Hydroxyl Functional Group Determination in Coal Tars and Pyrolysis of O-Methylated Coal," S.A.
Cannon, C.J. Chu, R.H. Hauge and J.L. Margrave. ACS, Division of Fuel Chemistry, 30:1, 258, (1985)

103)"Studies of Initial Reaction Steps in the Gasification of Coal," C.J. Chu, S.A. Cannon, R.H. Hauge and J.L.
Margrave. Final Technical Progress Report, Dept. of Energy, DE-AC21-83MC20685 (1985)

1986

104)"Activation of Alkanes and Cycloalkanes by Photoexcited Metal Atoms and Clusters," W.E. Billups, Z.H.
Kafafi, R.H. Hauge and J.L. Margrave. Proc., Vol. 3, 961-964 (1986), 4th Intl. Conf. on Homogeneous Catalysis,
Leningrad, Russia, September 1984

105)"Coal Pyrolysis Studies Using Matrix Isolation FTIR," C.J. Chu, S.A. Cannon, L. Fredin, R.H. Hauge and
J.L. Margrave. New Spectroscopic Techniques in Coal Science, NATO Advanced Studies Institute, (1986)

106)"Electronic Matrix Isolation Spectroscopic Studies of Group IVA Metal-Water Photochemistry," M.A.
Douglas, R.H. Hauge and J.L. Margrave. High Temperature Science, 22, 47-68, (1986)

107)"A Multisurface Matrix Isolation Apparatus," L. Fredin, Z.H. Kafafi, R.H. Hauge and J.L. Margrave. Appl.
Spec
., 40:5, 588-595 (1986)

108)"Matrix Isolation EPR Studies of Coal Tar Molecules," C.J. Chu, R.H. Hauge and J.L. Margrave. ACS Div.
Fuel Chem., Symp. on New Applications of Analytical Techniques to Fossil Fuels, Preprints, April 1986

109)"Photoactivation of Methyl Acetate by Chromium Atoms," W. E. Billups, John P. Bell, E. S. Kline, A. W.
Moorehead, Fred B. McCormick, R.H. Hauge and J.L. Margrave. Organometallics 5, 1917-1918 (1986)

110)"Reactions of Iron Atoms with Benzene and Cyclohexadiene in Argon Matrices: Iron-Benzene
Complexes and Photolytic Dehydrogenation of Cyclohexadiene
," D.W. Ball, Z.H. Kafafi, R.H. Hauge and
J.L. Margrave. J. Am. Chem. Soc. 108, 6621-6626 (1986)

111)"Studies of the Effects of O-Methylation on the Pyrolysis Behavior of Four Coals," C.J. Chu, S.A.
Cannon, R.H. Hauge and J.L. Margrave. Fuel Chemistry, 65, 1740-49 (1986)

112)"The Infrared Spectrum of Hexacarbonylbis(µ-carbonyl)(µ-methylene) di-iron Fe2(CO)6(µ-CO)2(µ-CH2)
in Cryogenic Matrices
," S.C. Chang, Z.H. Kafafi, K.H. Whitmire, W.E. Billups, R.H. Hauge and J.L. Margrave.
Inorg. Chem
., 25, 4530-4533 (1986)

113)"Reactions of Diatomic and Triatomic Metal Clusters of Iron and Copper with Dihydrogen in Inert
Matrices,
" Z. H. Kafafi, R.H. Hauge and J.L. Margrave. Proc., Int'l. Symposium on the Physics and Chemistry
of Small Clusters, a NATO Advanced Workshop, Richmond, Virginia, October 27-31, 1986

114)"Matrix-Isolation EPR Studies of Sn(II)-Fluoride," D. L. Perry, P. F. Meier, R.H. Hauge and J. L. Margrave.
Inorg. Chim. Acta. 116, L17-L19 (1986)

1987

115)"Infrared Absorption Characteristics of Hydroxyl Groups in Coal Tars," S.A. Cannon, C.J. Chu,
R.H. Hauge and J.L. Margrave. Fuel, 66, 51-54 (1987)

116)"Studies of Carbon Monoxide Activation with Atomic Lithium: I.R. Spectra of LiCO, LiOC, LiC2O2 and
Li2C2O2 in Cryogenic Matrices
," C.N. Krishnan, R.H. Hauge and J.L. Margrave. J. Mol. Structures 157,
187-196 (1987)

117)"FTIR Matrix Isolation Studies of the Reactions of Atomic and Diatomic Nickel with Acetylene and
Ethylene in Solid Argon. The Photosynthesis of Nickel Vinylidene
," E. S. Kline, Z. H. Kafafi, R.H. Hauge and
John L. Margrave. J. Am. Chem. Soc. 109, 2402-2409 (1987)

118)"Infrared Spectroscopy and Photochemistry of Iron-Ethylene Oxide in Cryogenic Matrices. The FTIR
Spectrum of Vinyliron Hydroxide
," Z. H. Kafafi, W. Edward Billups, R.H. Hauge and John L. Margrave. J. Am.
Chem. Soc
., 109, 4775-4780 (1987)

119)"Behavior of Concretes Under High Thermal Loads in Reactive Chemical Environments," G. P. Hansen,
R.H. Hauge and J. L. Margrave. Proceedings, Conference on Chemical Processes in Severe Nuclear Reactor
Accidents, Captiva Island, Florida, December 11, 1987

120)"Isolation and Characterization of ZnCH2 by FTIR Matrix Isolation Spectroscopy and Its Photolytic
Rearrangement to HZnCH
," Sou-Chan Chang, R.H. Hauge, J.L. Margrave and W.E. Billups. Chem. Comm.
1682-1684 (1987)

121)"The Isolation and Characterization of Copper Methylene (CuCH2) via FTIR Matrix Isolation," Sou-Chan
Chang, Z. H. Kafafi, W.E. Billups, R.H. Hauge and John L. Margrave. J. Am. Chem. Soc. 109, 4508-4513 (1987)

122)"The Isolation and Characterization of Copper Methylene via Matrix Isolation," Sou-Chan Chang, Z H.
Kafafi, R.H. Hauge ,J.L. Margrave, and W.E. Billups. Tetrahedron Lett. 28, 1733-1736 (1987)

1988

123)"Low Temperature Reactions of Methane with Photoexcited Nickel Atoms," Sou-Chan Chang,
W.E. Billups, R.H. Hauge and J.L. Margrave. Inorg. Chem. 27:1, 205-208 (1988)

124)"A Bibliography of Matrix-Isolation Spectroscopy, 1954-1985," D.W. Ball, Z.H. Kafafi, L. Fredin,
R.H. Hauge and J.L. Margrave. Rice Press, (1988) 643 pages

125)"Nickel and Cyclopropane Reactions and Photochemistry Using Matrix Isolation FTIR Spectroscopy,
Nickelacyclobutane Synthesis and Photofragmentation
," E.S. Klein, Z.H. Kafafi, R.H. Hauge and John L.
Margrave. Organometallics, Vol. 7, 1512-1516 (1988)

126)"Chemical Reaction of Carbon Atoms and Molecules from Laser-Induced Vaporization of Graphite, TaC
and EC
," B. J. Ortman, R.H. Hauge and J. L. Margrave. J. Quant. Spectrosc. Radiat. Transfer, Vol. 40, 439-447
(1988)

127)"Measurement of Temperature and Emissivity of Specularly Reflecting Glowing Bodies," G. P. Hansen,
S. Krishnan, R.H. Hauge and J. L. Margrave. Trans. Met. Soc., 19A, 1889-1894 (1988)

128)"Observations of the Dynamics of Electromagnetically Levitated Liquid Metals and Alloys at Elevated
Temperatures
," S. Krishnan, G. P. Hansen, R.H. Hauge and J. L. Margrave. Trans. Met. Soc., 19A, 1939-1943
(1988)

129)"Pyrolysis of Phenol-Formaldehyde Resins," C.J. Chu, E.S. Kline, R.H. Hauge and J.L. Margrave. Proc.,
DARPA Materials Research Council, July, 1988

130)"Surface Fluorination of Diamond," D. Patterson, R.H. Hauge and J.L. Margrave. Proc., DARPA Materials
Research Council, July, 1988

131)"Oxyfluoride Superconductors," D. Patterson, R.H. Hauge and J.L. Margrave. Proc., DARPA Materials
Research Council, July, 1988

132)"Matrix Isolation as a Tool for Studying Interstellar Chemical Reactions," D.W. Ball, B. Ortman,
R.H. Hauge and J.L. Margrave. Proc., Interstellar Dust Symposium, Santa Clara University, Stanford,
California, pp. 88-102, July 27, 1988

133)"Surface Fluorination of Diamonds," D.E. Patterson, R.H. Hauge and J.L. Margrave. Proc., 12th
International Symposium on Fluorine Chemistry, Santa Cruz, California, August 8-9, 1988

134)"Preparation of Oxyfluoride Superconductors," D.E. Patterson, R.H. Hauge and J.L. Margrave. Proc.
12th INt'l. Symposium on Fluorine Chemistry, Santa Cruz, California, August 8-9, 1988

135)"Derivatization of CFX," A.W. Moorehead, R.H. Hauge and J.L. Margrave. Proc. 12th International
Symposium on Fluorine Chemistry, Santa Cruz, California, Aug. 8-9, 1988

136)"Reactions and Photochemistry of Atomic and Diatomic Nickel with Water at 15K," M. Park, R.H. Hauge
and John L. Margrave. High Temperature Science 25, 1-15 (1988)

137)"Reactions of Nickel Atoms with Ammonia in Cryogenic Matrices," D.W. Ball, R.H. Hauge and J.L.
Margrave. High Temperature Science, 25, 95-101 (1988)

138)"Matrix-isolation Studies of the Reaction of Ni-atoms and Small Clusters with Ammonia,"D.W. Ball,
R.H. Hauge and John L. Margrave. High Temperature Science (accepted)

139)"The Characterization and Novel Low Temperature Reactions of FeCH2 and N2FeCH2," Sou-Chan
Chang, Z. H. Kafafi, R.H. Hauge and W. E. Billups. J. Am. Chem. Soc. 110, 7971-7980 (1988)

140)"Matrix Isolation FTIR Studies of Slow Pyrolysis Processes for Four Coals," C.J. Chu, S.A. Cannon,
R.H. Hauge and J.L. Margrave. Analytical and Applied Pyrolysis, 14, 115-134 (1988)

141)"Matrix Isolation FTIR Studies of Flash Pyrolysis of Four Coal Tars," C.J. Chu, R.H. Hauge and J.L.
Margrave. Analytical and Applied Pyrolysis, 14, 99-114 (1988)

142)"Fluorinated Diamond Films, Slabs and Grit," D.E. Patterson, R.H. Hauge and J.L. Margrave, Proc.,
Materials Research Society Symposium, Dec. 2, 1988, Boston, Mass vol. 140, pp. 351-256 (1988)

143)"Oxyfluoride Superconductors," D.E. Patterson and R.H. Hauge and J.L. Margrave. Proc. Materials Res.
Soc. Symposium, Boston, Mass. Dec. 2, 1988

144)"Chemical Reactions of Carbon Atoms and Molecules from Laser-Induced Vaporization of Graphite,
TaC and WC
," B.J. Ortman, L. Fredin, R.H.Hauge and J.L. Margrave, J. Quant. Spectrosc. Radiat. Transfer,
Vol. 40, 439-447 (1988)

1989

145)"Reactions of First Row Transition Metal Atoms and Small Clusters in Matrices," Lester Andrews and
Martin Moskovits, eds., Elsevier Science Publishers, New York, 1989, Z.H. Kafafi, R.H. Hauge and J.L.
Margrave. Chemistry and Physics of Matrix Isolated Species, Chapt. 10, pp. 277-302.

146)"Spectral Emissivities and Optical Properties of Electromagnetically Levitated Liquid Metals as
Functions of Temperature and Wavelength
," S. Krishnan, R.H. Hauge and J.L. Margrave. Proc., Conference
on Non-Contact Temperature Moments, Jet Propulsion Laboratory, Pasadena, California, Jan. 17-19, 1989

147)"Infrared Spectroscopic Studies of the Reactions of Cu and NH3 in Cryogenic Argon Matrices," D.W.
Ball, R.H. Hauge and J.L. Margrave. Inorganic Chemistry, 28, 1599-1601
(1989)
148)"Ellipsometric Method for the Measurement of Temperature and Optical Constants of Incandescent
Transition Metals
," S. Krishnan, G. P. Hansen, R.H. Hauge and J.L. Margrave. Applied Optics, 28, 1885-
1896
(1989)
149)"Spectral Emissivities of Liquid Transition Metals as Functions of Temperature and Wavelength," S.
Krishnan, G.P. Hansen, R.H. Hauge and J.L. Margrave. Proc., DARPA, Materials Research Council, July, 1989

150)"Glassy Fluorocarbons," A.W. Moorehead, R.H. Hauge and J.L. Margrave. Proc. DARPA Materials
Research Council, July, 1989

151)"Free-Standing Diamond Shapes-Cylinders, Hemispheres, Grids and Fibers," C.J. Chu, D.E. Patterson,
R.H. Hauge.and J.L. Margrave. Proc. DARPA Materials Research Council, July, 1989

152)"Ellipsometric Devices for Determination of Dielectric Constants, Indices of Refraction, Reflectivities,
Emissivities and True Temperatures of Solids and Liquids
," S. Krishnan, G. Hansen, R.H.Hauge and J.L.
Margrave. U.S. Patent Application.

153)"Direct Observation of C3v Bonding between Cobalt Atoms and Methane," Sou-Chan Chang, J.L.
Margrave, Z.H. Kafafi, R.H. Hauge and W.E. Billups. J. Am. Chem. Soc.

154)"Spectral Emissivities of Liquid Transition Metals as Functions of Temperature and Wavelength," S.
Krishnan, G.P. Hansen, R.H. Hauge and J.L. Margrave. Proc. Sixth Int'l Conference on High Temperature
Chemistry, National Institute of Science and Technology and IUPAC, Gaithersburg, Maryland, April 3-7, 1989,
High Temp. Science

155)"Mechanistic Studies of CVD Diamond Thin Film Growth," J.L. Margrave, J.C. Chu, D.E. Patterson and
R.H. Hauge. Lawrence Berkeley Laboratory Report, pp. 73-80, October 1989

156)"Simultaneous Brightness and Emissivity Measurement of Hot Surfaces," S. Krishnan, R.H. Hauge and
J.L. Margrave. Lawrence Berkeley Laboratory Report, pp. 65-72, October 1989


Publications 1990 to Present click Publications II